CO2 Injection for Enhanced Gas Recovery and Geological Storage of CO2 in the Long Coulee Glauconite F Pool, Alberta

Mehran Pooladi-Darvish, Huifang Hong, Sophie Theys, and Rudi Stocker / Fekete Associates Inc, Stefan Bachu / Energy Resources Conservation Board, and Shahin Dashtgard / Simon Fraser University

Copyright 2008, Society of Petroleum Engineers

This paper was prepared for presentation at the 2008 SPE Annual Technical Conference and Exhibition held in Denver, Colorado, USA, 21–24 September 2008.

Impure CO2 containing less than 2% H2S has been injected since 2002 into the depleted Long Coulee Glauconite F gas Pool in southeastern Alberta. Breakthrough was observed within one to three years in producing wells, leading to their abandonment. Simulation studies reported in this paper indicate that additional gas was recovered as a result of CO2 injection. An interesting observation at the breakthrough wells was that the CO2 broke through ahead of the H2S. The partitioning of the H2S and CO2 as they flow through the reservoir was studied in detail. One objective of the reported work is examination of interactions of the injected gas with the in-situ fluids and the displacement of the in-situ gas by the injection gas, for better understanding of the mechanisms involved in enhanced-gas recovery. Another objective of the work is to study factors that affect the spread of the injected gas in a depleted oil and gas reservoir and its implications with respected to CO2 geological storage. The results of this study indicate that at low pressures, the injected gas occupies a large reservoir volume and exhibits little density difference with the in-situ fluids, leading to rapid spread of the injected gas and early breakthrough. Also, it was found that in the case of Long Coulee Glauconite F gas Pool the well-spacing used for production did not allow a detailed geological characterization that was required for accurate prediction of breakthrough as a result of gas-gas displacement. Simulation studies, together with displacement experiments in the laboratory reported elsewhere, confirmed that the preferential solubility of H2S in the reservoir water led to stripping of the H2S at the leading gas front and it delayed its breakthrough relative to that of CO2. The implications of such chromatographic partitioning of H2S and CO2 in geological storage of impure CO2 streams are discussed.

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